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An Unexpected Photoelectronic Effect from [Co(en) 3 ] 2 (Zr 2 F 12 )(SiF 6 )⋅4 H 2 O, a Compound Containing an H‐Bonded Assembly of Discrete [Co(en) 3 ] 3+ , (Zr 2 F 12 ) 4− , and (SiF 6 ) 2− Ions
Author(s) -
Du Yu,
Yang Min,
Yu Jihong,
Pan Qinhe,
Xu Ruren
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200502514
Subject(s) - hydrothermal circulation , ion , materials science , physics , crystallography , chemistry , engineering , chemical engineering , quantum mechanics
Hydrogen‐bonded network : A hydrothermal synthesis delivers the titled compound, which consists of an H‐bonded network of discrete [Co(en) 3 ] 3+ , (Zr 2 F 12 ) 4− , and (SiF 6 ) 2− ions. It exhibits an unexpected photoelectronic effect in the near‐UV region (see figure).