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Diphenylphosphanylsulfoximines as Ligands in Iridium‐Catalyzed Asymmetric Imine Hydrogenations
Author(s) -
Moessner Christian,
Bolm Carsten
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200502482
Subject(s) - iridium , phosphine , imine , chemistry , catalysis , combinatorial chemistry , organic chemistry
Easily accessible phosphine‐substituted sulfoximines 2 have been applied in Ir‐catalyzed asymmetric hydrogenations of acylic N ‐arylated imines 1 . The amines 3 are formed under mild conditions in high yields with excellent ee values.