Formation of Iridabenzenes by Coupling of Iridacyclopentadienes and Alkenes | Zendy

Álvarez Eleuterio | Zendy; Paneque Margarita | Zendy; Poveda Manuel L. | Zendy; Rendón Nuria | Zendy

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Formation of Iridabenzenes by Coupling of Iridacyclopentadienes and Alkenes

Author(s) -

Álvarez Eleuterio,

Paneque Margarita,

Poveda Manuel L.,

Rendón Nuria

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200502437

Subject(s) - metallacycle , propene , coupling (piping) , chemistry , product (mathematics) , content (measure theory) , stereochemistry , computational chemistry , combinatorial chemistry , physics , organic chemistry , catalysis , materials science , x ray crystallography , mathematical analysis , geometry , mathematics , diffraction , optics , metallurgy

A new synthesis of iridabenzene species involves the coupling of MeCHCH 2 with iridacycles 1 and 2 . Surprisingly, the structure of the coupling product of the iridacyclopentadienes with propene ( 3 or 4 ) is highly susceptible to the nature of the substituents in the starting metallacycle.

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