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Formation of Iridabenzenes by Coupling of Iridacyclopentadienes and Alkenes
Author(s) -
Álvarez Eleuterio,
Paneque Margarita,
Poveda Manuel L.,
Rendón Nuria
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200502437
Subject(s) - metallacycle , propene , coupling (piping) , chemistry , product (mathematics) , content (measure theory) , stereochemistry , computational chemistry , combinatorial chemistry , physics , organic chemistry , catalysis , materials science , x ray crystallography , mathematical analysis , geometry , mathematics , diffraction , optics , metallurgy
A new synthesis of iridabenzene species involves the coupling of MeCHCH 2 with iridacycles 1 and 2 . Surprisingly, the structure of the coupling product of the iridacyclopentadienes with propene ( 3 or 4 ) is highly susceptible to the nature of the substituents in the starting metallacycle.