Recyclable Palladium Catalyst for Highly Selective α Alkylation of Ketones with Alcohols | Zendy

Kwon Min Serk | Zendy; Kim Namdu | Zendy; Seo Seong Hyeok | Zendy; Park In Soo | Zendy; Cheedrala Ravi Kumar | Zendy; Park Jaiwook | Zendy

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Recyclable Palladium Catalyst for Highly Selective α Alkylation of Ketones with Alcohols

Author(s) -

Kwon Min Serk,

Kim Namdu,

Seo Seong Hyeok,

Park In Soo,

Cheedrala Ravi Kumar,

Park Jaiwook

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200502422

Subject(s) - palladium , alkylation , catalysis , atmosphere (unit) , chemistry , hydroxide , alcohol oxidation , primary (astronomy) , organic chemistry , physics , astronomy , thermodynamics

An air‐stable, heterogeneous , and recyclable catalyst composed of palladium nanoparticles entrapped in aluminum hydroxide was applied to a highly selective α alkylation. A wide range of aliphatic and aromatic ketones and primary alcohols were coupled to prepare enones in an O 2 atmosphere and ketones in an argon atmosphere (see scheme).

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