High‐Temperature Synthesis of the Surprisingly Stable  C  1 ‐C 70 (CF 3 ) 10  Isomer with a  para  7 – meta – para  Ribbon of Nine C 6 (CF 3 ) 2  Edge‐Sharing Hexagons | Zendy

Kareev Ivan E. | Zendy; Kuvychko Igor V. | Zendy; Popov Alexey A. | Zendy; Lebedkin Sergey F. | Zendy; Miller Susie M. | Zendy; Anderson Oren P. | Zendy; Strauss Steven H. | Zendy; Boltalina Olga V. | Zendy

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High‐Temperature Synthesis of the Surprisingly Stable C 1 ‐C 70 (CF 3 ) 10 Isomer with a para 7 – meta – para Ribbon of Nine C 6 (CF 3 ) 2 Edge‐Sharing Hexagons

Author(s) -

Kareev Ivan E.,

Kuvychko Igor V.,

Popov Alexey A.,

Lebedkin Sergey F.,

Miller Susie M.,

Anderson Oren P.,

Strauss Steven H.,

Boltalina Olga V.

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200502419

Subject(s) - equator , ribbon , crystallography , yield (engineering) , enhanced data rates for gsm evolution , physics , chemistry , combinatorics , mathematics , geometry , thermodynamics , telecommunications , astronomy , computer science , latitude

From the equator to the pole : The high‐temperature, high‐yield C 1 isomer of C 70 (CF 3 ) 10 has an unprecedented structure. The CF 3 groups belong to a para 7 – meta – para ribbon of edge‐sharing C 6 (CF 3 ) 2 hexagons, which wraps around the equator of the C 70 cage and then climbs up to one of the poles. Calculations demonstrate that this isomer is more stable than the structures observed for C 70 Br 10 and C 70 ( t BuOO) 10 .

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