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Thermal [2+2] Intramolecular Cycloadditions of Fuller‐1,6‐enynes
Author(s) -
Martín Nazario,
Altable Margarita,
Filippone Salvatore,
MartínDomenech Angel,
Güell Mireia,
Solà Miquel
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200502404
Subject(s) - intramolecular force , cycloaddition , ring (chemistry) , fullerene , core (optical fiber) , chemistry , component (thermodynamics) , thermal , stereochemistry , materials science , physics , organic chemistry , quantum mechanics , composite material , catalysis , thermodynamics
More fused rings for fullerenes : Fuller‐1,6‐enynes are a peculiar class of 1,6‐enynes that involve a highly strained double‐bond component as well as a curved molecular surface. They undergo an unprecedented thermal [2+2] cycloaddition to afford products with three neighboring fused rings on one six‐membered ring of the C 60 core as shown in the scheme.