Thermal [2+2] Intramolecular Cycloadditions of Fuller‐1,6‐enynes | Zendy

Martín Nazario | Zendy; Altable Margarita | Zendy; Filippone Salvatore | Zendy; MartínDomenech Angel | Zendy; Güell Mireia | Zendy; Solà Miquel | Zendy

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Thermal [2+2] Intramolecular Cycloadditions of Fuller‐1,6‐enynes

Author(s) -

Martín Nazario,

Altable Margarita,

Filippone Salvatore,

MartínDomenech Angel,

Güell Mireia,

Solà Miquel

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200502404

Subject(s) - intramolecular force , cycloaddition , ring (chemistry) , fullerene , core (optical fiber) , chemistry , component (thermodynamics) , thermal , stereochemistry , materials science , physics , organic chemistry , quantum mechanics , composite material , catalysis , thermodynamics

More fused rings for fullerenes : Fuller‐1,6‐enynes are a peculiar class of 1,6‐enynes that involve a highly strained double‐bond component as well as a curved molecular surface. They undergo an unprecedented thermal [2+2] cycloaddition to afford products with three neighboring fused rings on one six‐membered ring of the C 60 core as shown in the scheme.

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