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Aluminum–Magnesium Complexes with Linearly Bridging Carbon Dioxide
Author(s) -
Chang ChungCheng,
Liao MinChun,
Chang TsuHsin,
Peng ShieMing,
Lee GeneHsiang
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200502400
Subject(s) - magnesium , aluminium , bridging (networking) , chemistry , content (measure theory) , carbon dioxide , inorganic chemistry , computer science , organic chemistry , mathematics , computer network , mathematical analysis
The linear μ(O,O′) bonding mode of CO 2 has been found for the first time in the magnesium–aluminum compounds [{R 2 Al(μ‐NSiMe 3 )(μ‐OSiMe 3 )Mg(thf) 2 (μ‐O 2 C)} 3 ] ( 1 (R=Me) and 2 (R=Et); THF ligands omitted), which were obtained by bubbling CO 2 through a mixture of AlR 3 and Mg[N(SiMe 3 ) 2 ] 2 in THF.
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