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Anion‐Induced Synthesis and Combinatorial Selection of Polypyrrolic Macrocycles
Author(s) -
Katayev Evgeny A.,
Pantos G. Dan,
Reshetova Marina D.,
Khrustalev Victor N.,
Lynch Vincent M.,
Ustynyuk Yuri A.,
Sessler Jonathan L.
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200502393
Subject(s) - analogy , chemistry , ion , combinatorial chemistry , selection (genetic algorithm) , titration , computer science , polymer chemistry , organic chemistry , artificial intelligence , philosophy , linguistics
Stimulating reactions : The anion‐induced synthesis of a new class of 2,6‐diamidopyridine–bipyrrole macrocyclic receptors that undergo combinatorial selection as a result of their interaction with anionic guests has been demonstrated (see picture of the interaction of bipyrrole fragments with a sulfate ion). The outcome of this stimulus‐driven reaction bears analogy to recent macrocycle‐forming strategies based on dynamic combinatorial processes.