High‐Pressure Probing of a Changeover in the Charge‐Transfer Mechanism for Intact Cytochrome  c  at Gold/Self‐Assembled Monolayer Junctions | Zendy

Khoshtariya Dimitri E. | Zendy; Dolidze Tina D. | Zendy; Sarauli David | Zendy; van Eldik Rudi | Zendy

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High‐Pressure Probing of a Changeover in the Charge‐Transfer Mechanism for Intact Cytochrome c at Gold/Self‐Assembled Monolayer Junctions

Author(s) -

Khoshtariya Dimitri E.,

Dolidze Tina D.,

Sarauli David,

van Eldik Rudi

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200502386

Subject(s) - changeover , monolayer , hydrostatic pressure , charge (physics) , chemistry , electron transfer , electrode , cytochrome c , chemical physics , nanotechnology , materials science , photochemistry , thermodynamics , computer science , physics , telecommunications , quantum mechanics , biochemistry , transmission (telecommunications) , mitochondrion

Free trade : The electron exchange of cytochrome c freely diffusing to gold electrodes modified by hydroxy‐terminated alkanethiol self‐assembled monolayers (SAMs; see picture) is examined by high‐pressure kinetic studies. The SAM thickness, solution viscosity, and hydrostatic pressure influence a changeover in the charge‐transfer mechanism and the corresponding kinetic response.

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