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Structural Transition and Tuning of tert ‐Butylamine Hydrate
Author(s) -
Kim DoYoun,
Lee Jongwon,
Seo YuTaek,
Ripmeester John A.,
Lee Huen
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200502376
Subject(s) - hydrate , content (measure theory) , phenomenon , chemistry , computer science , materials science , philosophy , mathematics , organic chemistry , epistemology , mathematical analysis
An unconventional hydrate promoter , t BuNH 2 , forms a double hydrate upon reacting with CH 4 (see picture). This double hydrate shows different storage capacities for CH 4 depending on the concentration of t BuNH 2 . Based on this phenomenon, a tuning concept for determining the optimum initial concentration of t BuNH 2 is proposed.
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