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Molecularly Assembled Nanostructures of a Redox‐Active Organogelator
Author(s) -
Akutagawa Tomoyuki,
Kakiuchi Keiko,
Hasegawa Tatsuo,
Noro Sinichiro,
Nakamura Takayoshi,
Hasegawa Hiroyuki,
Mashiko Sinro,
Becher Jan
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200502336
Subject(s) - tetrathiafulvalene , nanodot , amphiphile , nanotechnology , nanostructure , redox , chemistry , materials science , copolymer , organic chemistry , molecule , polymer
of an ethylenedithio group into an amphiphilic bis(tetrathiafulvalene) annulated macrocycle results in the formation of organogels which produce nanodot‐array structures in Langmuir–Blodgett films (see picture). Chemical oxidation of the sulphur‐containing π‐electron system afforded size‐controllable electrically conducting nanodot structures.