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Synthesis of Corrole Derivatives through Regioselective Ir‐Catalyzed Direct Borylation
Author(s) -
Hiroto Satoru,
Hisaki Ichiro,
Shinokubo Hiroshi,
Osuka Atsuhiro
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200502335
Subject(s) - corrole , borylation , regioselectivity , iridium , catalysis , chemistry , combinatorial chemistry , porphyrin , computer science , photochemistry , organic chemistry , alkyl , aryl
Showdown at the OK corrole : The direct borylation of corroles under iridium catalysis through CH activation proceeds with perfect regioselectivity and excellent yields. 2‐Borylated corroles allow an easy access (two steps) to directly linked corrole–porphyrin conjugates and other functionalized corroles (see scheme).