Crystal‐to‐Crystal Phase Transition in Self‐Assembled Mesoporous Iron Oxide Films | Zendy

Brezesinski Torsten | Zendy; Groenewolt Matthijs | Zendy; Antonietti Markus | Zendy; Smarsly Bernd | Zendy

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Crystal‐to‐Crystal Phase Transition in Self‐Assembled Mesoporous Iron Oxide Films

Author(s) -

Brezesinski Torsten,

Groenewolt Matthijs,

Antonietti Markus,

Smarsly Bernd

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200502332

Subject(s) - hematite , mesoporous material , copolymer , materials science , crystal (programming language) , phase transition , template , phase (matter) , iron oxide , chemical engineering , oxide , porosity , nanotechnology , crystal structure , goethite , crystallography , chemistry , computer science , polymer , composite material , organic chemistry , physics , metallurgy , adsorption , engineering , quantum mechanics , programming language , catalysis

Keeping order : Mesoporous crystalline iron oxide thin films were prepared by using special block copolymer templates. The optimized templating properties and temperature stability of the porogens allowed a crystal‐to‐crystal phase transition (from goethite to hematite) within the walls of the porous scaffold without disruption of the mesostructure.

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