Spiraling Steroids: Organic Crystals with Asymmetric Nanometer‐Scale Channels | Zendy

Sisson Adam L. | Zendy; del Amo Sanchez Vicente | Zendy; Magro Germinal | Zendy; Griffin Alex M. E. | Zendy; Shah Shilen | Zendy; Charmant Jonathan P. H. | Zendy; Davis Anthony P. | Zendy

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Spiraling Steroids: Organic Crystals with Asymmetric Nanometer‐Scale Channels

Author(s) -

Sisson Adam L.,

del Amo Sanchez Vicente,

Magro Germinal,

Griffin Alex M. E.,

Shah Shilen,

Charmant Jonathan P. H.,

Davis Anthony P.

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200502330

Subject(s) - nanometre , nanotechnology , variety (cybernetics) , fluorine , chemistry , ion , materials science , combinatorial chemistry , crystallography , computer science , physics , organic chemistry , optics , artificial intelligence

Crystals with broad robust channels are rare, especially if self‐assembled without the aid of metal ions. Three such crystals were prepared based on a common steroid motif. The channels formed are chiral, directional, aligned, and wide enough (>1 nm) to accept a variety of guests (see picture; red: oxygen, blue: nitrogen, green: fluorine).

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