A Neutron Diffraction Study of [OsClH 3 (PPh 3 ) 3 ]: A Complex Containing a Highly “Stretched” Dihydrogen Ligand | Zendy

Yousufuddin Muhammed | Zendy; Wen Ting Bin | Zendy; Mason Sax A. | Zendy; McIntyre Garry J. | Zendy; Jia Guochen | Zendy; Bau Robert | Zendy

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A Neutron Diffraction Study of [OsClH 3 (PPh 3 ) 3 ]: A Complex Containing a Highly “Stretched” Dihydrogen Ligand

Author(s) -

Yousufuddin Muhammed,

Wen Ting Bin,

Mason Sax A.,

McIntyre Garry J.,

Jia Guochen,

Bau Robert

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200502297

Subject(s) - neutron diffraction , crystallography , diffraction , dihydrogen complex , ligand (biochemistry) , materials science , neutron , x ray crystallography , chemistry , physics , crystal structure , optics , nuclear physics , metal , hydride , metallurgy , biochemistry , receptor

Elastic bonds : The structure of [OsHCl(η 2 ‐H 2 )(PPh 3 ) 3 ] has been determined by neutron diffraction (see figure). The complex presents an unusual H⋅⋅⋅H contact of 1.48(2) Å and can be regarded either as a highly stretched dihydrogen complex or as a compressed dihydride complex.

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