[Tl 8 ] 6−  in Cs 8 Tl 8 O: A Naked Eight‐Vertex  closo ‐Deltaeder as a Cluster Anion | Zendy

Karpov Andrey | Zendy; Jansen Martin | Zendy

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[Tl 8 ] 6− in Cs 8 Tl 8 O: A Naked Eight‐Vertex closo ‐Deltaeder as a Cluster Anion

Author(s) -

Karpov Andrey,

Jansen Martin

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200502283

Subject(s) - octahedron , crystallography , cluster (spacecraft) , tetrahedron , ion , electron counting , valence (chemistry) , thallium , chemistry , valence electron , vertex (graph theory) , physics , crystal structure , electron , inorganic chemistry , combinatorics , mathematics , nuclear physics , organic chemistry , computer science , programming language , graph

Structures to count on : The title compound crystallizes in a unique crystal‐structure type which can be regarded as a rock‐salt derivative composed of a suboxide group [OCs 6+2 ] 6+ (yellow) and a novel thallium cluster [Tl 8 ] 6− (blue). The valence electron count of the eight‐vertex cluster obeys the Wade–Mingos condensation rules when considering it as a condensation of an octahedron with two tetrahedra.

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