Staggered to Eclipsed Conformational Rearrangement of [Co 2 (CO) 6 (PPh 3 ) 2 ] in the Solid State: An X‐ray Diffraction Study at High Pressure and Low Temperature | Zendy

Casati Nicola | Zendy; Macchi Piero | Zendy; Sironi Angelo | Zendy

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Staggered to Eclipsed Conformational Rearrangement of [Co 2 (CO) 6 (PPh 3 ) 2 ] in the Solid State: An X‐ray Diffraction Study at High Pressure and Low Temperature

Author(s) -

Casati Nicola,

Macchi Piero,

Sironi Angelo

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200502241

Subject(s) - chemistry , diffraction , crystallography , high pressure , phase (matter) , x ray crystallography , solid state , thermodynamics , physics , organic chemistry , optics

Under pressure : characterization of the high‐pressure phase of crystalline [Co 2 (CO) 6 (PPh 3 ) 2 ] has provided the first structural evidence for the transformation from a staggered to eclipsed arrangement of the equatorial carbonyl ligands in a dimeric transition‐metal complex (see picture). A comparison with the same phenomenon observed at low temperature (though arrested in the very early stages) is presented.

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