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Two‐Step Spin Conversion in a Cyanide‐Bridged Ferrous Square
Author(s) -
Nihei Masayuki,
Ui Mayumi,
Yokota Mizuho,
Han Lingqin,
Maeda Atsushi,
Kishida Hideo,
Okamoto Hiroshi,
Oshio Hiroki
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200502216
Subject(s) - cyanide , spin crossover , ferrous , square (algebra) , spin (aerodynamics) , molecule , chemistry , crossover , spinning , crystallography , nanotechnology , physics , materials science , computer science , inorganic chemistry , organic chemistry , polymer chemistry , mathematics , thermodynamics , geometry , artificial intelligence
Spinning out : A cyanide‐bridged molecular square (see picture) has been isolated and found to undergo thermally induced, two‐step spin crossover. Molecules with more than one spin‐crossover site are suitable building blocks for multistepped molecular switches.