A Three‐Dimensional Metal–Organic Framework with an Unprecedented Octahedral Building Unit | Zendy

Livage Carine | Zendy; Guillou Nathalie | Zendy; Chaigneau Julienne | Zendy; Rabu Pierre | Zendy; Drillon Marc | Zendy; Férey Gérard | Zendy

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A Three‐Dimensional Metal–Organic Framework with an Unprecedented Octahedral Building Unit

Author(s) -

Livage Carine,

Guillou Nathalie,

Chaigneau Julienne,

Rabu Pierre,

Drillon Marc,

Férey Gérard

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200502185

Subject(s) - octahedron , cobalt , architecture , crystallography , unit (ring theory) , scale (ratio) , metal , metal organic framework , chemistry , materials science , computer science , nanotechnology , physics , inorganic chemistry , organic chemistry , crystal structure , mathematics , history , adsorption , quantum mechanics , mathematics education , archaeology

Unusual octahedral hexamers built up from triangular, corner‐linked cobalt trimers (see figure), form the basis of a novel three‐dimensional cobalt isophthalate obtained by a solvothermal route. This structure provides a new example of the concept of scale chemistry, in which an {Na 6 Co 6 O 26 } “super octahedron” is connected in a classical ReO 3 architecture.

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