Spin Transfer and Solvato‐/Thermochromism Induced by Intramolecular Electron Transfer in a Purely Organic Open‐Shell System | Zendy

Nishida Shinsuke | Zendy; Morita Yasushi | Zendy; Fukui Kozo | Zendy; Sato Kazunobu | Zendy; Shiomi Daisuke | Zendy; Takui Takeji | Zendy; Nakasuji Kazuhiro | Zendy

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Spin Transfer and Solvato‐/Thermochromism Induced by Intramolecular Electron Transfer in a Purely Organic Open‐Shell System

Author(s) -

Nishida Shinsuke,

Morita Yasushi,

Fukui Kozo,

Sato Kazunobu,

Shiomi Daisuke,

Takui Takeji,

Nakasuji Kazuhiro

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200502180

Subject(s) - thermochromism , intramolecular force , shell (structure) , electron transfer , chemistry , acceptor , spin (aerodynamics) , electron , open shell , photochemistry , materials science , stereochemistry , condensed matter physics , physics , organic chemistry , thermodynamics , quantum mechanics , composite material

Doctoring spin : Spin transfer and solvato‐/thermochromism have been observed in a purely organic open‐shell system comprising electron‐donor and ‐acceptor moieties, in which a 6‐oxophenalenoxyl neutral radical is directly linked with tetrathiafulvalene. Intramolecular electron transfer (IET, see scheme) causes this interconversion, which can be controlled by a moderate change in the solvent environment and temperature.

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