Oxygen Storage at the Metal/Oxide Interface of Catalyst Nanoparticles | Zendy

Schalow Tobias | Zendy; Laurin Mathias | Zendy; Brandt Björn | Zendy; Schauermann Swetlana | Zendy; Guimond Sebastien | Zendy; Kuhlenbeck Helmut | Zendy; Starr David E. | Zendy; Shaikhutdinov Shamil K. | Zendy; Libuda Jörg | Zendy; Freund  HansJoachim | Zendy

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Oxygen Storage at the Metal/Oxide Interface of Catalyst Nanoparticles

Author(s) -

Schalow Tobias,

Laurin Mathias,

Brandt Björn,

Schauermann Swetlana,

Guimond Sebastien,

Kuhlenbeck Helmut,

Starr David E.,

Shaikhutdinov Shamil K.,

Libuda Jörg,

Freund HansJoachim

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200502160

Subject(s) - x ray photoelectron spectroscopy , oxide , catalysis , oxygen , scanning tunneling microscope , materials science , oxygen storage , chemical engineering , nanoparticle , metal , nanotechnology , chemistry , metallurgy , organic chemistry , engineering

Holding its breath : Small Pd particles on an Fe 3 O 4 support reversibly store large quantities of oxygen in the form of a thin Pd oxide layer at the particle/support interface. Oxygen from this reservoir can be released during oxidation reactions, as shown by a combination of molecular beam methods, scanning tunneling microscopy, and photoelectron spectroscopy.

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