Intramolecular Hydroamination of Functionalized Alkenes and Alkynes with a Homogenous Zinc Catalyst | Zendy

Zulys Agustino | Zendy; Dochnahl Maximilian | Zendy; Hollmann Dirk | Zendy; Löhnwitz Karolin | Zendy; Herrmann JostSteffen | Zendy; Roesky Peter W. | Zendy; Blechert Siegfried | Zendy

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Intramolecular Hydroamination of Functionalized Alkenes and Alkynes with a Homogenous Zinc Catalyst

Author(s) -

Zulys Agustino,

Dochnahl Maximilian,

Hollmann Dirk,

Löhnwitz Karolin,

Herrmann JostSteffen,

Roesky Peter W.,

Blechert Siegfried

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200502006

Subject(s) - hydroamination , intramolecular force , isopropyl , chemistry , zinc , catalysis , combinatorial chemistry , organic chemistry

Simple and versatile : A new zinc complex catalyzes the intramolecular hydroamination of nonactivated alkynes and alkenes (see example in scheme; {( i Pr) 2 ATI}= N ‐isopropyl‐2‐(isopropylamino)troponiminato). The catalyst is relatively robust, exhibits excellent activities, and tolerates various functional groups such as ethers, thioethers, and amides.

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