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Intramolecular Hydroamination of Functionalized Alkenes and Alkynes with a Homogenous Zinc Catalyst
Author(s) -
Zulys Agustino,
Dochnahl Maximilian,
Hollmann Dirk,
Löhnwitz Karolin,
Herrmann JostSteffen,
Roesky Peter W.,
Blechert Siegfried
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200502006
Subject(s) - hydroamination , intramolecular force , isopropyl , chemistry , zinc , catalysis , combinatorial chemistry , organic chemistry
Simple and versatile : A new zinc complex catalyzes the intramolecular hydroamination of nonactivated alkynes and alkenes (see example in scheme; {( i Pr) 2 ATI}= N ‐isopropyl‐2‐(isopropylamino)troponiminato). The catalyst is relatively robust, exhibits excellent activities, and tolerates various functional groups such as ethers, thioethers, and amides.