Premium
Unsaturated Fatty Alcohol Derivatives as a Source of Substituted Allylzirconocene
Author(s) -
Chinkov Nicka,
Levin Anat,
Marek Ilan
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200501946
Subject(s) - moiety , alcohol , double bond , chemistry , allylic rearrangement , fatty alcohol , allylic alcohol , ether , tandem , organic chemistry , medicinal chemistry , catalysis , materials science , composite material
From A to Z : A llyl z irconocenes have been easily prepared in a one‐pot procedure through a tandem allylic CH activation–β‐elimination reaction from unsaturated fatty alcohol and ether starting materials (see scheme). The reaction proceeds rapidly under mild condition and is insensitive to the length of the carbon tether between the double bond and the alcohol moiety.