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N ‐Methylhydroxylamido(1−)‐ and Nitrosomethaneruthenium Complexes Derived from Nitrosyl Complexes: Reversible N‐Protonation of an N‐Coordinated Nitrosoalkane
Author(s) -
Kura Satoshi,
Kuwata Shigeki,
Ikariya Takao
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200501916
Subject(s) - hydroxylamine , chemistry , protonation , nitrite , nitroxyl , ammonia , nitrogen , combinatorial chemistry , medicinal chemistry , photochemistry , organic chemistry , nitrate , ion
Interconversion of organonitrogen oxides : Nitrosyl, nitrosoalkane, and hydroxylamido(1−) ligands are interconverted on an organoruthenium platform (see structure and scheme). These stepwise and sequential reactions provide insights into the mechanism of the biological nitrite–ammonia interconversion, a major process in the inorganic nitrogen cycle in which nitric oxide, nitroxyl, and hydroxylamine have been invoked as intermediates.