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Azine‐Bridged Octanuclear Copper( II ) Complexes Assembled with a One‐Stranded Ditopic Thiocarbohydrazone Ligand
Author(s) -
Dragancea Diana,
Arion Vladimir B.,
Shova Sergiu,
Rentschler Eva,
Gerbeleu Nicolae V.
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200501807
Subject(s) - ligand (biochemistry) , chemistry , copper , azine , flexibility (engineering) , combinatorial chemistry , stereochemistry , crystallography , receptor , biochemistry , organic chemistry , statistics , mathematics
Metallomacrocyclic arrays containing eight copper( II ) centers (see picture; green Cu, blue N, red O, yellow S) were obtained by using a heptadentate thiocarbohydrazone ligand with a particular conformational and configurational flexibility, as well as an appropriate arrangement of metal‐binding sites, coordination ability, and acid–base properties.