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A High‐Throughput Investigation of the Role of pH, Temperature, Concentration, and Time on the Synthesis of Hybrid Inorganic–Organic Materials
Author(s) -
Forster Paul M.,
Stock Norbert,
Cheetham Anthony K.
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200501766
Subject(s) - chemistry , throughput , cobalt , phase diagram , phase (matter) , kinetic control , kinetic energy , reaction conditions , chemical engineering , inorganic chemistry , organic chemistry , catalysis , computer science , physics , quantum mechanics , engineering , telecommunications , wireless
Four reaction parameters and their effects on the formation of cobalt succinate phases were studied by high‐throughput methods. In addition to identifying two new phases, we show that higher reaction temperatures lead to products containing less water, more basic conditions favor increasingly condensed M‐O‐M networks (see phase diagram), and depending on the reaction time the products are formed under either kinetic or thermodynamic control.