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Cu 2+ ‐Mediated Dehydrogenative Coupling and Hydroxylation of an N‐Heterocyclic Ligand: From Generation of a New Tetratopic Ligand to the Designed Assembly of Three‐Dimensional Copper( I ) Coordination Polymers
Author(s) -
Hu Sheng,
Chen JingCai,
Tong MingLiang,
Wang Bo,
Yan YunXin,
Batten Stuart R.
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200501753
Subject(s) - ligand (biochemistry) , propane , hydroxylation , chemistry , copper , molar ratio , hydrothermal circulation , topology (electrical circuits) , stereochemistry , catalysis , organic chemistry , receptor , chemical engineering , mathematics , combinatorics , biochemistry , engineering , enzyme
The hydrothermal reaction of 1,3‐di(4‐pyridyl)propane with Cu(OH) 2 in the presence of 1,4‐cyclohexanedicarboxylic acid and dilute HCl generates an unprecedented tetratopic ligand (chtpy) and a family of interesting coordination networks in situ (see scheme). The topological diversification of the Cu I –chtpy nets can be controlled simply by changing the molar ratio of the starting materials.