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Thermolysis of a Hybrid Organic–Inorganic Supramolecular Coordination Assembly: Templating the Formation of Nanostructured Fibrous Materials and Carbon‐Based Microcapsules
Author(s) -
Schmitt Wolfgang,
Hill Jonathan P.,
Malik Sharali,
Volkert Cynthia A.,
Ichinose Izumi,
Anson Christopher E.,
Powell Annie K.
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200501748
Subject(s) - supramolecular chemistry , hybrid material , thermal decomposition , template , nanotechnology , yield (engineering) , materials science , decomposition , carbon fibers , self assembly , scanning electron microscope , chemical engineering , chemistry , organic chemistry , crystal structure , composite number , composite material , engineering
Burning a honeycomb : An exceptional hybrid organic–inorganic coordination assembly with an extended 3D structure that contains vast separated organic and inorganic regions has been prepared (see picture of its supramolecular structure and a scanning electron micrograph image). This hybrid is used as a template in thermolysis reactions to yield nano‐ and microsized products whose properties are determined by those of the precursor compounds.