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Asymmetric Conjugate Addition of Organozinc Compounds to α,β‐Unsaturated Aldehydes and Ketones with [2.2]Paracyclophaneketimine Ligands without Added Copper Salts
Author(s) -
Bräse Stefan,
Höfener Sebastian
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200501732
Subject(s) - conjugate , copper , chemistry , organic chemistry , medicinal chemistry , mathematics , mathematical analysis
The ligand makes it possible: The asymmetric conjugate addition of diethylzinc to α,β‐unsaturated aldehydes and ketones occurs with catalytic amounts of the paracyclophaneketimine ligand 1 without further additives.
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