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Versatile Hypervalent‐Iodine( III )‐Catalyzed Oxidations with m ‐Chloroperbenzoic Acid as a Cooxidant
Author(s) -
Dohi Toshifumi,
Maruyama Akinobu,
Yoshimura Misaki,
Morimoto Koji,
Tohma Hirofumi,
Kita Yasuyuki
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200501688
Subject(s) - hypervalent molecule , iodine , catalysis , reagent , chemistry , transformation (genetics) , organic chemistry , combinatorial chemistry , biochemistry , gene
A new and effective use of hypervalent iodine( III ) reagents as catalysts involves the transformation of iodoarenes 1 into hypervalent iodine( III ) species 2 with meta ‐chloroperbenzoic acid ( m CPBA) as the appropriate cooxidant. With observed turnover numbers greater than 70, this procedure paves the way for broader application of these useful oxidants in organic synthesis.