Regioselective Hypervalent‐Iodine( III )‐Mediated Dearomatizing Phenylation of Phenols through Direct Ligand Coupling | Zendy

OzanneBeaude Aurélie | Zendy; Quideau Stéphane | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Regioselective Hypervalent‐Iodine( III )‐Mediated Dearomatizing Phenylation of Phenols through Direct Ligand Coupling

Author(s) -

OzanneBeaude Aurélie,

Quideau Stéphane

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200501638

Subject(s) - hypervalent molecule , regioselectivity , chemistry , phenols , ligand (biochemistry) , iodine , coupling (piping) , stereochemistry , phenol , combinatorial chemistry , organic chemistry , catalysis , receptor , biochemistry , mechanical engineering , engineering

Dearomatization : Treatment of phenols and naphthols substituted at the ortho position by a small electron‐donating group D with chlorodiphenyl‐λ 3 ‐iodane leads to their regioselective ortho phenylation to give cyclohexa‐2,4‐dienone derivatives (see scheme). The mechanism of this reaction involves a nonradical direct coupling of the ligands.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research