Dithiaethyneporphyrin: An Atypical [18]Triphyrin(4.1.1) Frame for Contracted Porphyrins | Zendy

Berlicka Anna | Zendy; LatosGrażyński Lechosław | Zendy; Lis Tadeusz | Zendy

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Dithiaethyneporphyrin: An Atypical [18]Triphyrin(4.1.1) Frame for Contracted Porphyrins

Author(s) -

Berlicka Anna,

LatosGrażyński Lechosław,

Lis Tadeusz

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200501635

Subject(s) - joins , moiety , thiophene , acetylene , chemistry , distortion (music) , stereochemistry , crystallography , computer science , organic chemistry , telecommunications , programming language , amplifier , bandwidth (computing)

Fusion of the structural motifs 21,23‐dithiaporphyrin and acetylene yields the 18‐π‐aromatic [18]triphyrin(4.1.1) framework (see structure; C gray, N blue, S yellow). The butyne moiety that joins the two thiophene rings reveals a slight distortion from linearity, showing a bowlike deformation directed out of the macrocycle.

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