Rhodium‐Mediated Formation of Peroxides from Dioxygen: Isolation of Hydroperoxo, Silylperoxo, and Methylperoxo Intermediates | Zendy

Ahijado Marcel | Zendy; Braun Thomas | Zendy; Noveski Daniel | Zendy; Kocher Nikolaus | Zendy; Neumann Beate | Zendy; Stalke Dietmar | Zendy; Stammler HansGeorg | Zendy

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Rhodium‐Mediated Formation of Peroxides from Dioxygen: Isolation of Hydroperoxo, Silylperoxo, and Methylperoxo Intermediates

Author(s) -

Ahijado Marcel,

Braun Thomas,

Noveski Daniel,

Kocher Nikolaus,

Neumann Beate,

Stalke Dietmar,

Stammler HansGeorg

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200501615

Subject(s) - rhodium , chemistry , hydrogen peroxide , peroxide , trimethylsilyl , molecular oxygen , oxygen , catalysis , stereochemistry , polymer chemistry , photochemistry , organic chemistry

Out of thin air , a rhodium complex converts molecular oxygen into hydrogen peroxide, bis(trimethylsilyl) peroxide, and methyl hydroperoxide. Intermediate η 1 ‐hydroperoxo and η 1 ‐silylperoxo, and η 1 ‐methylperoxo complexes have been isolated. Another η 1 ‐methylperoxo (see picture) and an η 1 ‐hydroperoxo complex have been characterized by X‐ray crystallography.

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