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Tin‐Free Radical Carbonylation: Thiol Ester Synthesis Using Alkyl Allyl Sulfone Precursors, Phenyl Benzenethiosulfonate, and CO
Author(s) -
Kim Sangmo,
Kim Sunggak,
Otsuka Noboru,
Ryu Ilhyong
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200501606
Subject(s) - tin , carbonylation , thiol , alkyl , sulfone , chemistry , organic chemistry , polymer chemistry , catalysis , carbon monoxide
Remove contents from tin … Thiol esters have been successfully synthesized through tin‐free radical carbonylation (see scheme; V‐40=initiator). This approach can be further extended to sequential radical reactions involving cyclization, carbonylation, and trapping of acyl radicals by phenyl benzenethiosulfonate.