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Charge‐Transfer Isomers and Mixed‐Valence Properties
Author(s) -
Crutchley Robert J.
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200501598
Subject(s) - valence (chemistry) , charge (physics) , ruthenium , transfer (computing) , chemical physics , chemistry , computational chemistry , materials science , physics , computer science , organic chemistry , quantum mechanics , catalysis , parallel computing
The unusual suspects : By using a series of ruthenium clusters of the type [{Ru 3 O(μ‐CH 3 COO) 6 (CO)L′}(μ‐ L ){Ru 3 O(μ‐CH 3 COO) 6 (CO)L′′}] (see picture) it has been possible to identify the existence of charge‐transfer isomers and establish them as identifiable chemical entities that exist in dynamic equilibrium.