The Photochemical Reactivity of the “Photo‐Inert” Tungsten (Fischer) Carbene Complexes | Zendy

Fernández Israel | Zendy; Sierra Miguel A. | Zendy; GómezGallego Mar | Zendy; Mancheño María J. | Zendy; Cossío Fernando P. | Zendy

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The Photochemical Reactivity of the “Photo‐Inert” Tungsten (Fischer) Carbene Complexes

Author(s) -

Fernández Israel,

Sierra Miguel A.,

GómezGallego Mar,

Mancheño María J.,

Cossío Fernando P.

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200501590

Subject(s) - carbene , tungsten , inert , reactivity (psychology) , chemistry , photochemistry , transition metal carbene complex , polymer chemistry , organic chemistry , catalysis , medicine , alternative medicine , pathology

The light fantastic : Tungsten( 0 ) Fischer carbene complexes, previously considered to be photo‐inert, produce, by adequately choosing the ligands, three classes of photoproducts (see scheme). Thus, irradiation of tetracarbonyltungsten( 0 ) carbene complexes 1 leads to syn ‐metalated imines 2 , amino complexes 3 , and α‐amino esters 4 . Reasonable reaction pathways are proposed for all these processes.

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