Premium
Ultramacrocyclization through Reversible Catenation
Author(s) -
Hori Akiko,
Sawada Tomohisa,
Yamashita Kenichi,
Fujita Makoto
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200501559
Subject(s) - catenation , nanoscopic scale , ring (chemistry) , computer science , chemistry , crystallography , nanotechnology , combinatorial chemistry , materials science , organic chemistry , dna , biochemistry
Extreme macrocyclization! An ultramacrocyclic structure with 238 non‐hydrogen atoms in its backbone is obtained quantitatively through the reversible catenation of a double‐loop compound that contains Pd II ‐clipped coordination rings at both ends (see structure). The Pd II ring can be regarded as a nanoscale reaction center that is available for connecting nanoscopic components without high entropy costs.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom