Preparation of Heterobimetallic Oxide–Hydroxide–Hydrogensulfides [LAl(OH)(μ‐O)MCp 2 (SH)] (M=Ti, Zr) | Zendy

Jancik Vojtech | Zendy; Roesky Herbert W. | Zendy

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Preparation of Heterobimetallic Oxide–Hydroxide–Hydrogensulfides [LAl(OH)(μ‐O)MCp 2 (SH)] (M=Ti, Zr)

Author(s) -

Jancik Vojtech,

Roesky Herbert W.

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200501509

Subject(s) - hydroxide , chalcogen , oxide , derivative (finance) , hydrolysis , chemistry , ring (chemistry) , medicinal chemistry , composition (language) , nuclear chemistry , inorganic chemistry , crystallography , organic chemistry , financial economics , economics , linguistics , philosophy

Heterobimetallic sulfides of composition [LAl(μ‐S) 2 MCp 2 ] (M=Ti, Zr) react smoothly with two equivalents of water by ring opening and chalcogen exchange to form the heterobimetallic oxide–hydroxide–hydrogensulfides [LAl(OH)(μ‐O)MCp 2 (SH)] (Ti derivative shown). The presence of the hydrolysis intermediate [LAl(SH)(μ‐O)MCp 2 (SH)] in the reaction mixture confirms the proposed pathway.

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