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Preparation of Heterobimetallic Oxide–Hydroxide–Hydrogensulfides [LAl(OH)(μ‐O)MCp 2 (SH)] (M=Ti, Zr)
Author(s) -
Jancik Vojtech,
Roesky Herbert W.
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200501509
Subject(s) - hydroxide , chalcogen , oxide , derivative (finance) , hydrolysis , chemistry , ring (chemistry) , medicinal chemistry , composition (language) , nuclear chemistry , inorganic chemistry , crystallography , organic chemistry , financial economics , economics , linguistics , philosophy
Heterobimetallic sulfides of composition [LAl(μ‐S) 2 MCp 2 ] (M=Ti, Zr) react smoothly with two equivalents of water by ring opening and chalcogen exchange to form the heterobimetallic oxide–hydroxide–hydrogensulfides [LAl(OH)(μ‐O)MCp 2 (SH)] (Ti derivative shown). The presence of the hydrolysis intermediate [LAl(SH)(μ‐O)MCp 2 (SH)] in the reaction mixture confirms the proposed pathway.