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Oxidative Addition of NH 3 to a Transition‐Metal Complex: A Key Step for the Metal‐Mediated Derivatization of Ammonia?
Author(s) -
Braun Thomas
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200501505
Subject(s) - ammonia , chemistry , transition metal , yield (engineering) , derivatization , metal , catalysis , oxidative addition , oxidative phosphorylation , combinatorial chemistry , inorganic chemistry , organic chemistry , materials science , metallurgy , high performance liquid chromatography , biochemistry
Bond cleavage with model character? The oxidative addition of ammonia to a transition‐metal complex to yield a terminal amido complex was achieved for the first time recently (see scheme). This model reaction might provide new pathways to use ammonia as a feedstock in catalytic reactions.