Premium
Control of Differential Inclusion Complexation in the Solid State by Seed Crystals
Author(s) -
Yoshizawa Kazuhiro,
Toyota Shinji,
Toda Fumio,
Chatziefthimiou Spyros,
Giastas Petros,
Mavridis Irene M.,
Kato Masako
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200501364
Subject(s) - differential inclusion , inclusion (mineral) , sowing , seed crystal , solid state , state (computer science) , crystallography , differential (mechanical device) , crystal (programming language) , chemistry , phase (matter) , chemical engineering , mineralogy , mathematics , agronomy , physics , thermodynamics , single crystal , computer science , biology , organic chemistry , engineering , mathematical analysis , algorithm , programming language
Sowing the seeds : Complexation of rac ‐ 1 in the solid state with a guest such as Et 2 O in the gas phase proceeds in the presence of a seed crystal of the inclusion complex (see scheme). For example, passing Et 2 O over a mixture of 1 and a seed of 1 ⋅(Et 2 O) 3 gives rise to exclusive formation of the 1:3 complex.