Two Molecular Tapes Consisting of Serial or Parallel Azido‐Bridged Eight‐Membered Copper Rings | Zendy

Zhang YuanZhu | Zendy; Wei HaiYan | Zendy; Pan Feng | Zendy; Wang ZheMing | Zendy; Chen ZhiDa | Zendy; Gao Song | Zendy

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Two Molecular Tapes Consisting of Serial or Parallel Azido‐Bridged Eight‐Membered Copper Rings

Author(s) -

Zhang YuanZhu,

Wei HaiYan,

Pan Feng,

Wang ZheMing,

Chen ZhiDa,

Gao Song

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200501327

Subject(s) - acetonitrile , methanol , copper , azide , ferromagnetism , crystallography , ion , chemistry , scheme (mathematics) , stereochemistry , physics , condensed matter physics , mathematics , organic chemistry , mathematical analysis

Magnetic attraction : The exotic 1D molecular tapes [Cu 4 (N 3 ) 8 (CH 3 CN) 3 (bzp) 2 ] n ( 1 ) and [Cu 5 (N 3 ) 10 (bzp) 2 ] n ( 2 ) were obtained from a solution of methanol or methanol/acetonitrile (see scheme; bzp=2‐benzoylpyridyl). The end‐on azide bridges in 1 transmit ferromagnetic interaction, whereas in 2 , the central copper center of a linear Cu 5 unit is antiferromagnetically coupled with its neighboring Cu ions.

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