Supramolecular Click Chemistry with a Bisammonium‐C 60  Substrate and a Ditopic Crown Ether Host | Zendy

Hahn Uwe | Zendy; Elhabiri Mourad | Zendy; Trabolsi Ali | Zendy; Herschbach Haiko | Zendy; Leize Emmanuelle | Zendy; Van Dorsselaer Alain | Zendy; AlbrechtGary AnneMarie | Zendy; Nierengarten JeanFrançois | Zendy

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Supramolecular Click Chemistry with a Bisammonium‐C 60 Substrate and a Ditopic Crown Ether Host

Author(s) -

Hahn Uwe,

Elhabiri Mourad,

Trabolsi Ali,

Herschbach Haiko,

Leize Emmanuelle,

Van Dorsselaer Alain,

AlbrechtGary AnneMarie,

Nierengarten JeanFrançois

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200501249

Subject(s) - crown ether , supramolecular chemistry , host–guest chemistry , click chemistry , chemistry , schematic , non covalent interactions , ether , stereochemistry , polymer chemistry , molecule , ion , organic chemistry , engineering , hydrogen bond , electronic engineering

All clicking into place : Self‐complementarity between a bis(crown ether) derivative and a bisammonium fullerene leads to the formation of a stable noncovalent macrocyclic 1:1 complex (see schematic representation). The binding constant for this complex is three orders of magnitude larger than that for other closely related systems as a result of the two‐center host–guest topography.

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