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New Iodination Reactions of Saturated Hydrocarbons
Author(s) -
Barluenga José,
CamposGómez Esther,
Rodríguez David,
GonzálezBobes Francisco,
González José M.
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200501195
Subject(s) - hypervalent molecule , chemistry , iodine , sodium azide , reagent , acetic anhydride , halogenation , aqueous solution , organic chemistry , trimethylsilyl , azide , catalysis
Unactivated CH bonds react with iodine when exposed to trimethylsilyl azide in the presence of a hypervalent iodine reagent or, alternatively, to aqueous H 2 O 2 , acetic anhydride, and sodium azide (see scheme).