A Neutral Mixed‐Valent Conducting Polymer Formed by Electron Transfer between Metal d and Ligand π Orbitals | Zendy

Mitsumi Minoru | Zendy; Goto Hidekazu | Zendy; Umebayashi Shunsuke | Zendy; Ozawa Yoshiki | Zendy; Kobayashi Mototada | Zendy; Yokoyama Toshihiko | Zendy; Tanaka Hisaaki | Zendy; Kuroda Shinichi | Zendy; Toriumi Koshiro | Zendy

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A Neutral Mixed‐Valent Conducting Polymer Formed by Electron Transfer between Metal d and Ligand π Orbitals

Author(s) -

Mitsumi Minoru,

Goto Hidekazu,

Umebayashi Shunsuke,

Ozawa Yoshiki,

Kobayashi Mototada,

Yokoyama Toshihiko,

Tanaka Hisaaki,

Kuroda Shinichi,

Toriumi Koshiro

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200501189

Subject(s) - atomic orbital , rhodium , molecular orbital , electron transfer , chemistry , metal , ligand (biochemistry) , electron , molecule , crystallography , physics , organic chemistry , quantum mechanics , biochemistry , receptor , catalysis

Frontier‐orbital design aided in the preparation of the novel neutral linear chain rhodium( I , II ) complex [Rh(3,6‐dbdiox‐4,5‐Cl 2 )(CO) 2 ] ∞ (see picture), in which the mixed‐valent state is formed by electron transfer between metal d and semiquinonate π* orbitals (3,6‐dbdiox‐4,5‐Cl 2 : semiquinonate or catecholate of 3,6‐di‐ tert ‐butyl‐4,5‐dichloro‐1,2‐benzoquinone). This compound exhibits high conductivity (17–34 S cm −1 ) at room temperature in spite of its being a neutral molecule.

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