A Stable Aluminacyclopropene LAl(η 2 ‐C 2 H 2 ) and Its End‐On Azide Insertion to an Aluminaazacyclobutene | Zendy

Zhu Hongping | Zendy; Chai Jianfang | Zendy; Fan Hongjun | Zendy; Roesky Herbert W. | Zendy; He Cheng | Zendy; Jancik Vojtech | Zendy; Schmidt HansGeorg | Zendy; Noltemeyer Mathias | Zendy; Merrill William A. | Zendy; Power Philip P. | Zendy

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A Stable Aluminacyclopropene LAl(η 2 ‐C 2 H 2 ) and Its End‐On Azide Insertion to an Aluminaazacyclobutene

Author(s) -

Zhu Hongping,

Chai Jianfang,

Fan Hongjun,

Roesky Herbert W.,

He Cheng,

Jancik Vojtech,

Schmidt HansGeorg,

Noltemeyer Mathias,

Merrill William A.,

Power Philip P.

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200500899

Subject(s) - azide , acetylene , chemistry , medicinal chemistry , physics , organic chemistry

Not all down‐to‐Earth : A stable aluminacyclopropene LAl(η 2 ‐C 2 H 2 ) 1 was isolated from the reaction of LAl with C 2 H 2 . Further reaction of 1 with C 2 H 2 results in terminal CCH and CHCH 2 groups at the Al center. The end‐on insertion of an azide into one AlC bond in 1 leads to the first aluminaazacyclobutene 2 . These reactions can be considered prebiotic, as Al I species and acetylene are found in outer space.

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