Platinum‐Mediated Oxidative Addition and Reductive Elimination of Imidazolium Salts at C4 and C5 | Zendy

Bacciu Deborha | Zendy; Cavell Kingsley J. | Zendy; Fallis Ian A. | Zendy; Ooi Liling | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Platinum‐Mediated Oxidative Addition and Reductive Elimination of Imidazolium Salts at C4 and C5

Author(s) -

Bacciu Deborha,

Cavell Kingsley J.,

Fallis Ian A.,

Ooi Liling

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200500884

Subject(s) - carbene , imes , chemistry , reductive elimination , oxidative addition , silver salts , oxidative phosphorylation , platinum , medicinal chemistry , combinatorial chemistry , organic chemistry , catalysis , biochemistry

Wrong way round : Imidazolium salts blocked at C2 undergo oxidative addition to a Pt 0 center at C4/C5 (see scheme; nbe=norbornene, IMes=1,3‐bis(2,4,6‐trimethylphenyl)imidazolin‐2‐ylidene). The resulting carbene ligands, which are bound the “wrong way” are susceptible, in common with their “normal” counterparts, to reductive elimination reactions to regenerate Pt 0 complexes and imidazolium salts.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research