Synthesis and Self‐Assembly of Rod–Rod Hybrid Poly(γ‐benzyl  L ‐glutamate)‐ block ‐Polyisocyanide Copolymers | Zendy

Kros Alexander | Zendy; Jesse Wim | Zendy; Metselaar Gerald A. | Zendy; Cornelissen Jeroen J. L. M. | Zendy

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Synthesis and Self‐Assembly of Rod–Rod Hybrid Poly(γ‐benzyl L ‐glutamate)‐ block ‐Polyisocyanide Copolymers

Author(s) -

Kros Alexander,

Jesse Wim,

Metselaar Gerald A.,

Cornelissen Jeroen J. L. M.

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200500877

Subject(s) - copolymer , self assembly , polymer chemistry , rod , materials science , isocyanide , chemistry , stereochemistry , polymer , nanotechnology , composite material , medicine , alternative medicine , pathology

Connecting rods : Rigid rod–rod block copolymers are synthesized from peptide and polyisocyanide blocks (see picture: blue=poly(γ‐benzyl L ‐glutamate); red=poly(methylbenzyl isocyanide) or poly( L ‐isocyanoalanyl‐ L ‐alanine methyl ester). The polyisocyanide helix has side arms organized in a parallel β‐sheet (light blue). Some copolymers self‐assemble into ordered layers of hollow capsules.

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