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CuH in a Bottle: A Convenient Reagent for Asymmetric Hydrosilylations
Author(s) -
Lipshutz Bruce H.,
Frieman Bryan A.
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200500800
Subject(s) - reagent , bottle , chemistry , hydride , hydrosilylation , organic chemistry , catalysis , materials science , composite material , hydrogen
Bottled for freshness : [{( R )‐DTBM‐segphos}CuH] (see formula; DTBM=3,5‐di‐ tert‐ butyl‐4‐methoxy) generated in situ represents the first reported copper hydride reagent that can be stored and used over time without loss of activity in several types of asymmetric hydrosilylation reactions.