Triangular Geometrical and Magnetic Motifs Uniquely Linked on a Spherical Capsule Surface | Zendy

Müller Achim | Zendy; Todea Ana Maria | Zendy; van Slageren Joris | Zendy; Dressel Martin | Zendy; Bögge Hartmut | Zendy; Schmidtmann Marc | Zendy; Luban Marshall | Zendy; Engelhardt Larry | Zendy; Rusu Mariana | Zendy

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Triangular Geometrical and Magnetic Motifs Uniquely Linked on a Spherical Capsule Surface

Author(s) -

Müller Achim,

Todea Ana Maria,

van Slageren Joris,

Dressel Martin,

Bögge Hartmut,

Schmidtmann Marc,

Luban Marshall,

Engelhardt Larry,

Rusu Mariana

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200500697

Subject(s) - spheres , spins , surface (topology) , magnetism , physics , spin (aerodynamics) , crystallography , geometry , condensed matter physics , materials science , chemistry , mathematics , thermodynamics , astronomy

Sphere we go : A spherical capsule is prepared simply by the interaction of linkers to pentagonal structural units. The metal centers (M) of the {(Mo VI )Mo VI 5 } 12 M 30 type Keplerates formed (M=V IV , Fe III ) describe an icosidodecahedron (see picture). For M=Fe III the magnetic configuration of the 30 spin centers (colored spheres) can be pictured geometrically in terms of three sets, each of 10 spins, with different angular orientations (arrows). With M=V IV the compound behaves according to the demands of quantum mechanics and a clear geometrical picture of the magnetism is not possible.

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