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Heteroligated Rh I Tweezer Complexes
Author(s) -
Brown Aaron M.,
Ovchinnikov Maxim V.,
Mirkin Chad A.
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200500689
Subject(s) - variety (cybernetics) , chemistry , ligand (biochemistry) , center (category theory) , halide , content (measure theory) , scheme (mathematics) , stereochemistry , computer science , crystallography , organic chemistry , biochemistry , artificial intelligence , receptor , mathematical analysis , mathematics
A halide‐induced ligand rearrangement around a Rh I center can be used for the preparation of heteroligated tweezer‐type complexes. By using a variety of P,S‐ and P,O‐hemilabile ligands, the complexes can be interconverted between four different Rh I ‐coordination environments (see scheme).