Heteroligated Rh I  Tweezer Complexes | Zendy

Brown Aaron M. | Zendy; Ovchinnikov Maxim V. | Zendy; Mirkin Chad A. | Zendy

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Heteroligated Rh I Tweezer Complexes

Author(s) -

Brown Aaron M.,

Ovchinnikov Maxim V.,

Mirkin Chad A.

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200500689

Subject(s) - variety (cybernetics) , chemistry , ligand (biochemistry) , center (category theory) , halide , content (measure theory) , scheme (mathematics) , stereochemistry , computer science , crystallography , organic chemistry , biochemistry , artificial intelligence , receptor , mathematical analysis , mathematics

A halide‐induced ligand rearrangement around a Rh I center can be used for the preparation of heteroligated tweezer‐type complexes. By using a variety of P,S‐ and P,O‐hemilabile ligands, the complexes can be interconverted between four different Rh I ‐coordination environments (see scheme).

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